Compatibilizer

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Drop deformation, breakup, and coalescence with compatibilizer

The effect of copolymers on the breakup and coalescence of polybutadiene ~PB! drops in polydimethylsiloxane ~PDMS! is studied using a four-roll mill flow cell. Copolymers are produced at the interface by a reaction between functionalized homopolymers. They reduce the interfacial tension and thus enhance breakup; they also inhibit coalescence of drops. Under the conditions of our experiments, th...

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Strain recovery of model immiscible blends without compatibilizer

The rheological properties of blends of immiscible homopolymers have received much attention in recent years (Tucker and Moldenaers 2002). Several publications have been devoted to examining the relationship between the rheology and morphology of two-phase blends. A key strategy employed by many researchers was to conduct experiments on ‘‘model’’ blends that were comprised of rheologically-simp...

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Effects of compatibilizer on immiscible polymer blends near phase inversion

e consider the effects of adding a PIB-PDMS diblock copolymer as a compatibilizer in model lends composed of polyisobutylene PIB and polydimethylsiloxane PDMS . The ratio of PIB to DMS was varied from 20:80 to 80:20 and, hence, these blends are dubbed “concentrated” blends. ost experiments were conducted on blends containing 0.01 or 0.1 wt. % compatibilizer. All lends had a droplet-matrix morph...

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Influence of Compatibilizer on Blends Degradation During Processing

The thermomechanical degradation of blends made from polypropylene and polystyrene, with or without compatibilizer, was studied using an internal mixer coupled to a torque rheometer. The blends processed without compatibilizer presented regular and expected results regarding torque reduction, with evidence of chain scission. The blends processed with the block copolymer of styrene and butadiene...

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Toward an alternative compatibilizer for PLA/cellulose composites: grafting of xyloglucan with PLA.

Poly(L-lactic acid) (PLLA) chains were grafted on xyloglucan substrates via ring-opening polymerization of the L-lactide monomer. Different parameters such as the nature of the substrate (native or modified xyloglucan) and the substrate/monomer ratios were varied in the synthesis to achieve different lengths of the grafted chains. A range of experimental techniques including infrared spectrosco...

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ژورنال

عنوان ژورنال: Seikei-Kakou

سال: 2011

ISSN: 0915-4027,1883-7417

DOI: 10.4325/seikeikakou.23.494